A modified CuO/CeO2 catalyst was prepared by surfactant-assisted impregnation method and showed better catalytic activity for low temperature CO oxidation than that from conventional impregnation method. The physicoch...A modified CuO/CeO2 catalyst was prepared by surfactant-assisted impregnation method and showed better catalytic activity for low temperature CO oxidation than that from conventional impregnation method. The physicochemical properties of different CuO/CeO2 catalysts were characterized by thermogravimetrie and differential scanning calorimetric measurements （TG-DSC）, X-ray diffraction （XRD）, N2 adsorpti0n-desorption, Raman spectroscopy, H2 temperature-programmed reduction （H2-TPR）, tern- perature-programmed desorption of 02 （O2-TPD）, and diffuse reflectance infrared Fourier transform spectroscopy （DRIFTS）. The re- sults suggested that the addition of hexadecyl trimethyl ammonium bromide （CTAB） into the impregnation solution could improve the dispersion of CuO species, which could facilitate Cu2＋ incorporating into CeO2 lattice and strengthened the synergistic effects between CuO and CeO2, making the lattice oxygen more active, and eventually resulting in enhanced activity for CO oxidation.展开更多
基金supported by the National Natural Science Foundation of China(21273150)‘‘Shu Guang’’Project(10GG23)of Shanghai Municipal Education CommissionShanghai Education Development Foundation
文摘A modified CuO/CeO2 catalyst was prepared by surfactant-assisted impregnation method and showed better catalytic activity for low temperature CO oxidation than that from conventional impregnation method. The physicochemical properties of different CuO/CeO2 catalysts were characterized by thermogravimetrie and differential scanning calorimetric measurements （TG-DSC）, X-ray diffraction （XRD）, N2 adsorpti0n-desorption, Raman spectroscopy, H2 temperature-programmed reduction （H2-TPR）, tern- perature-programmed desorption of 02 （O2-TPD）, and diffuse reflectance infrared Fourier transform spectroscopy （DRIFTS）. The re- sults suggested that the addition of hexadecyl trimethyl ammonium bromide （CTAB） into the impregnation solution could improve the dispersion of CuO species, which could facilitate Cu2＋ incorporating into CeO2 lattice and strengthened the synergistic effects between CuO and CeO2, making the lattice oxygen more active, and eventually resulting in enhanced activity for CO oxidation.
