Oxidation pressure leaching was proposed to selectively dissolve Li from spent LiFePO_(4) batteries in a stoichiometric sulfuric acid solution.Using O_(2) as an oxidant and stoichiometric sulfuric acid as leaching age...Oxidation pressure leaching was proposed to selectively dissolve Li from spent LiFePO_(4) batteries in a stoichiometric sulfuric acid solution.Using O_(2) as an oxidant and stoichiometric sulfuric acid as leaching agent,above 97% of Li was leached into the solution,whereas more than 99% of Fe remained in the leaching residue,enabling a relatively low cost for one-step separation of Li and Fe.And then,by adjusting the pH of leachate,above 95% of Li was recovered in the form of the Li_(3)PO_(4) product through iron removal and chemical precipitation of phosphate.展开更多
基金the financial supports from the National Natural Science Foundation of China(Nos.51804083,52104395,21906031)the Natural Science Foundation of Guangdong Province,China(No.2019A1515011628)+1 种基金the Science and Technology Planning Project of Guangdong Province,China(No.2017B090907026)the Special Program of Guangdong Academy of Sciences,China(Nos.2019GDASYL-0103069,2020GDASYL-0104027,2020GDASYL-0302004,2020GDASYL-0302009,2021GDASYL-0302004)。
文摘Oxidation pressure leaching was proposed to selectively dissolve Li from spent LiFePO_(4) batteries in a stoichiometric sulfuric acid solution.Using O_(2) as an oxidant and stoichiometric sulfuric acid as leaching agent,above 97% of Li was leached into the solution,whereas more than 99% of Fe remained in the leaching residue,enabling a relatively low cost for one-step separation of Li and Fe.And then,by adjusting the pH of leachate,above 95% of Li was recovered in the form of the Li_(3)PO_(4) product through iron removal and chemical precipitation of phosphate.
