Alloy nanostructures supporting localized surface plasmon resonances has been widely used as efficient photocatalysts,but the microscopic mechanism of alloy compositions enhancing the catalytic efficiency is still unc...Alloy nanostructures supporting localized surface plasmon resonances has been widely used as efficient photocatalysts,but the microscopic mechanism of alloy compositions enhancing the catalytic efficiency is still unclear.By using time-dependent density functional theory(TDDFT),we analyze the real-time reaction processes of plasmon-mediated H_(2) splitting on linear Ag-Au alloy chains when exposed to femtosecond laser pulses.It is found that H_(2) splitting rate depends on the position and proportion of Au atoms in alloy chains,which indicates that specially designed Ag-Au alloy is more likely to induce the reaction than pure Ag chain.Especially,more electrons directly transfer from the alloy chain to the anti-bonding state of H_(2),thereby accelerating the H_(2) splitting reaction.These results establish a theoretical foundation for comprehending the microscopic mechanism of plasmon-induced chemical reaction on the alloy nanostructures.展开更多
The plasmon-induced nonlinear response has attracted great attention in micro-nano optics and optoelectronics applications,yet the underlying microscopic mechanism remains elusive.In this study,the nonlinear response ...The plasmon-induced nonlinear response has attracted great attention in micro-nano optics and optoelectronics applications,yet the underlying microscopic mechanism remains elusive.In this study,the nonlinear response of gold nanoclusters when exposed to a femtosecond laser pulse was investigated using time-dependent density functional theory.It was observed that the third-order tunneling current was augmented in plasmonic dimers,owing to a greater number of electrons in the dimer being excited from occupied to unoccupied states.These findings provide profound theoretical insights and enable the realization of accurate regulation and control of nonlinear effects induced by plasmons at the atomic level.展开更多
We report the experimental preparations of the absolute ground states of 87Rb and 40K atoms （｜F = 1, mF = 1 ） ＋ ｜F = 9/2, rnF ： -9/2）） by means of the radio-frequency and microwave adiabatic rapid passages, an...We report the experimental preparations of the absolute ground states of 87Rb and 40K atoms （｜F = 1, mF = 1 ） ＋ ｜F = 9/2, rnF ： -9/2）） by means of the radio-frequency and microwave adiabatic rapid passages, and the observation of magnetic Feshbach resonances in an ultracold mixture of bosonic STRb and fermionic 40K atoms between 0 T and 6.0 × 10^-2 T, including 7 homonuclear and 4 heteronuclear Feshbach resonances. The resonances are identified by the abrupt trap loss of atoms induced by the strong inelastic three-body collisions. These Feshbach resonances should enable the experimental control of interspecies interactions.展开更多
Localized surface plasmon has been extensively studied and used for the photocatalysis of various chemical reactions.However,the different contributions between plasmon resonance and interband transition in photocatal...Localized surface plasmon has been extensively studied and used for the photocatalysis of various chemical reactions.However,the different contributions between plasmon resonance and interband transition in photocatalysis has not been well understood.Here,we study the photothermal and hot electrons effects for crystal transformation by combining controlled experiments with numerical simulations.By photo-excitation of Na YF4:Eu^(3+)@Au composite structure,it is found that the plasmonic catalysis is much superior to that of interband transition in the experiments,owing to the hot electrons generated by plasmon decay more energetic to facilitate the reaction.We emphasize that the energy level of hot electrons plays an essential role for improving the photocatalytic activity.The results provide guidelines for improving the efficiency of plasmonic catalysis in future experimental design.展开更多
We investigate sympathetic cooling fermions 40K by evaporatively cooling bosonic 87Rb atoms in a magnetic trap with microwave and radio frequency induced evaporations in detail. The mixture of bosonic and fermionic at...We investigate sympathetic cooling fermions 40K by evaporatively cooling bosonic 87Rb atoms in a magnetic trap with microwave and radio frequency induced evaporations in detail. The mixture of bosonic and fermionic atoms is prepared in their polarized spin states IF = 9/2, mF = 9/2） for 40K and IF = 2, mF=2〉 for 87Rb, which is trapped in Quadrupole-Ioffe-Configuration trap. Comparing microwave with radio frequency evaporatively cooling bosonic STRb atoms with sympathetically cooling Fermi gas 40K, we find that the presence of rubidium atoms in the [2, 1} Zeeman states, which are generated in the evaporative process, gives rise to a significant loss of 40K due to inelastic collisions. Thus, the rubidium atoms populated in the [2, 1} Zeeman states should be removed in order to effectively perform sympathetically cooling 40K with the evaporatively cooled STRb atoms.展开更多
We create weakly bound Feshbach molecules in ultracold Fermi gas40K by sweeping a magnetic field across a broad Feshbach resonance point 202.2 G with a rate of 20 ms/G and perform the dissociation process using radio-...We create weakly bound Feshbach molecules in ultracold Fermi gas40K by sweeping a magnetic field across a broad Feshbach resonance point 202.2 G with a rate of 20 ms/G and perform the dissociation process using radio-frequency(RF) technology. From RF spectroscopy, we obtain the binding energy of the weakly bound molecules in the vicinity of Feshbach resonance. Our measurement also shows that the number of atoms generated from the dissociation process is different at various magnetic fields with the same RF amplitude, which gives us a deeper understanding of weakly bound Feshbach molecules.展开更多
基金Project supported by the National Key Research and Development Program of China(Grant Nos.2020YFA0211300 and 2021YFA1201500)the National Natural Science Foundation of China(Grant Nos.U22A6005,92150110,12074237,and 12304426)+2 种基金the Natural Science Foundation of Shaanxi Province,China(Grant No.2024JC-JCQN-07)the Fundamental Science Foundation of Shaanxi Province,China(Grant No.22JSZ010)the Fundamental Research Funds for Central Universities(Grant Nos.GK202201012 and GK202308001).
文摘Alloy nanostructures supporting localized surface plasmon resonances has been widely used as efficient photocatalysts,but the microscopic mechanism of alloy compositions enhancing the catalytic efficiency is still unclear.By using time-dependent density functional theory(TDDFT),we analyze the real-time reaction processes of plasmon-mediated H_(2) splitting on linear Ag-Au alloy chains when exposed to femtosecond laser pulses.It is found that H_(2) splitting rate depends on the position and proportion of Au atoms in alloy chains,which indicates that specially designed Ag-Au alloy is more likely to induce the reaction than pure Ag chain.Especially,more electrons directly transfer from the alloy chain to the anti-bonding state of H_(2),thereby accelerating the H_(2) splitting reaction.These results establish a theoretical foundation for comprehending the microscopic mechanism of plasmon-induced chemical reaction on the alloy nanostructures.
基金Project supported by the National Key R&D Program of China (Grant Nos.2020YFA0211300 and 2021YFA1201500)the National Natural Science Foundation of China (Grant Nos.U22A6005,92150110,12074237,and 12304426)+2 种基金the Natural Science Foundation of Shaanxi Province (Grant No.2024JC-JCQN-07)the Fundamental Science Foundation of Shaanxi (Grant No.22JSZ010)the Fundamental Research Funds for Central Universities (Grant Nos.GK202201012 and GK202308001)。
文摘The plasmon-induced nonlinear response has attracted great attention in micro-nano optics and optoelectronics applications,yet the underlying microscopic mechanism remains elusive.In this study,the nonlinear response of gold nanoclusters when exposed to a femtosecond laser pulse was investigated using time-dependent density functional theory.It was observed that the third-order tunneling current was augmented in plasmonic dimers,owing to a greater number of electrons in the dimer being excited from occupied to unoccupied states.These findings provide profound theoretical insights and enable the realization of accurate regulation and control of nonlinear effects induced by plasmons at the atomic level.
基金supported by the National Natural Science Foundation for Distinguished Young Scholars of China (Grant No. 10725416)the National Basic Research Program of China (Grant No. 2006CB921101)the National Natural Science Foundation of China for Excellent Research Team, China (Grant No. 60821004)
文摘We report the experimental preparations of the absolute ground states of 87Rb and 40K atoms （｜F = 1, mF = 1 ） ＋ ｜F = 9/2, rnF ： -9/2）） by means of the radio-frequency and microwave adiabatic rapid passages, and the observation of magnetic Feshbach resonances in an ultracold mixture of bosonic STRb and fermionic 40K atoms between 0 T and 6.0 × 10^-2 T, including 7 homonuclear and 4 heteronuclear Feshbach resonances. The resonances are identified by the abrupt trap loss of atoms induced by the strong inelastic three-body collisions. These Feshbach resonances should enable the experimental control of interspecies interactions.
基金the National Key Research and Development Program of China(Grant No.2020YFA0211300)the National Natural Science Foundation of China(Grant Nos.92050112,12074237,and 12004233)the Fundamental Research Funds for Central Universities,China(Grant Nos.GK202103010and GK202103018)。
文摘Localized surface plasmon has been extensively studied and used for the photocatalysis of various chemical reactions.However,the different contributions between plasmon resonance and interband transition in photocatalysis has not been well understood.Here,we study the photothermal and hot electrons effects for crystal transformation by combining controlled experiments with numerical simulations.By photo-excitation of Na YF4:Eu^(3+)@Au composite structure,it is found that the plasmonic catalysis is much superior to that of interband transition in the experiments,owing to the hot electrons generated by plasmon decay more energetic to facilitate the reaction.We emphasize that the energy level of hot electrons plays an essential role for improving the photocatalytic activity.The results provide guidelines for improving the efficiency of plasmonic catalysis in future experimental design.
基金Project supported by the National Science Foundation for Distinguished Young Scholars of China(Grant No.10725416)the National Basic Research Program of China(Grant No.2006CB921101 and 2011CB921601)the National Science Foundation NSFC Project for Excellent Research Team,China(Grant No.60821004)
文摘We investigate sympathetic cooling fermions 40K by evaporatively cooling bosonic 87Rb atoms in a magnetic trap with microwave and radio frequency induced evaporations in detail. The mixture of bosonic and fermionic atoms is prepared in their polarized spin states IF = 9/2, mF = 9/2） for 40K and IF = 2, mF=2〉 for 87Rb, which is trapped in Quadrupole-Ioffe-Configuration trap. Comparing microwave with radio frequency evaporatively cooling bosonic STRb atoms with sympathetically cooling Fermi gas 40K, we find that the presence of rubidium atoms in the [2, 1} Zeeman states, which are generated in the evaporative process, gives rise to a significant loss of 40K due to inelastic collisions. Thus, the rubidium atoms populated in the [2, 1} Zeeman states should be removed in order to effectively perform sympathetically cooling 40K with the evaporatively cooled STRb atoms.
基金Project supported by the National Basic Research Program of China （Grant No. 2011CB921601）, the National Natural Science Foundation of China （Grant No. 11234008）, the Project for Excellent Research Team of China （Grant No. 61121064）, and the Doctoral Program Foundation of Ministry of Education, China （Grant No. 20111401130001）.
文摘We create weakly bound Feshbach molecules in ultracold Fermi gas40K by sweeping a magnetic field across a broad Feshbach resonance point 202.2 G with a rate of 20 ms/G and perform the dissociation process using radio-frequency(RF) technology. From RF spectroscopy, we obtain the binding energy of the weakly bound molecules in the vicinity of Feshbach resonance. Our measurement also shows that the number of atoms generated from the dissociation process is different at various magnetic fields with the same RF amplitude, which gives us a deeper understanding of weakly bound Feshbach molecules.
