A sol-gel freezing-drying method was utilized to prepare energetic nanocomposites based on 2, 4, 6, 8,10, 12-hexanitro-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane(CL-20) with 3, 3-Bis(azidomethyl) oxetanetetrahydrofuran c...A sol-gel freezing-drying method was utilized to prepare energetic nanocomposites based on 2, 4, 6, 8,10, 12-hexanitro-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane(CL-20) with 3, 3-Bis(azidomethyl) oxetanetetrahydrofuran copolymer(BAMO-THF) as energetic gel matrix. Scanning electron microscopy(SEM),X-ray diffraction(XRD), Raman, Fourier-transform infrared spectroscopy(FT-IR) and differential thermal analyser(DTA) were utilized to characterize the structure and property of the resultant energetic nanocomposites. Compared with raw CL-20, the average particle sizes of CL-20 in CL-20/BAMO-THF energetic nanocomposites were decreased to nano scale and the morphologies of CL-20 were also changed from prismatic to spherical. FT-IR detection revealed that CL-20 particles were recrystallized in BAMO-THF gel matrix during the freezing-drying process. The thermal decomposition behaviors of the energetic nanocomposites were investigated as well. The thermolysis process of CL-20/BAMO-THF nanocomposites was enhanced and the activation energy was lower compared with that of raw CL-20,indicating that CL-20/BAMO-THF nanocomposites showed high thermolysis activity. The impact sensitivity tests indicated that CL-20/BAMO-THF energetic nanocomposites presented low sensitivity performance.展开更多
Near-Earth Asteroids(NEA)impose potential major disaster to humanity.Planetary defense is an inevitable requirement for the survival of human civilization.In recent years,China has made rapid progress in planetary def...Near-Earth Asteroids(NEA)impose potential major disaster to humanity.Planetary defense is an inevitable requirement for the survival of human civilization.In recent years,China has made rapid progress in planetary defense research,which has won the attention of the government and attracted more and more scholars and organizations.This paper summarizes the research progress in planetary defense in China in recent years,including the fireball events in China,academic activities and policy planning,monitoring and warning technology,onorbit defense technology,impact hazard assessment,international cooperation and science popularization.展开更多
文摘A sol-gel freezing-drying method was utilized to prepare energetic nanocomposites based on 2, 4, 6, 8,10, 12-hexanitro-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane(CL-20) with 3, 3-Bis(azidomethyl) oxetanetetrahydrofuran copolymer(BAMO-THF) as energetic gel matrix. Scanning electron microscopy(SEM),X-ray diffraction(XRD), Raman, Fourier-transform infrared spectroscopy(FT-IR) and differential thermal analyser(DTA) were utilized to characterize the structure and property of the resultant energetic nanocomposites. Compared with raw CL-20, the average particle sizes of CL-20 in CL-20/BAMO-THF energetic nanocomposites were decreased to nano scale and the morphologies of CL-20 were also changed from prismatic to spherical. FT-IR detection revealed that CL-20 particles were recrystallized in BAMO-THF gel matrix during the freezing-drying process. The thermal decomposition behaviors of the energetic nanocomposites were investigated as well. The thermolysis process of CL-20/BAMO-THF nanocomposites was enhanced and the activation energy was lower compared with that of raw CL-20,indicating that CL-20/BAMO-THF nanocomposites showed high thermolysis activity. The impact sensitivity tests indicated that CL-20/BAMO-THF energetic nanocomposites presented low sensitivity performance.
基金Supported by the Beijing Municipal Science and Technology Commission(Z181100002918004)the Strategic Priority Program on Space Science(XDA15014900)the Civil Aerospace Preliminary Research Project(KJSP2020020101,CAS)。
文摘Near-Earth Asteroids(NEA)impose potential major disaster to humanity.Planetary defense is an inevitable requirement for the survival of human civilization.In recent years,China has made rapid progress in planetary defense research,which has won the attention of the government and attracted more and more scholars and organizations.This paper summarizes the research progress in planetary defense in China in recent years,including the fireball events in China,academic activities and policy planning,monitoring and warning technology,onorbit defense technology,impact hazard assessment,international cooperation and science popularization.
