Poly(acrylic acid-co-acrylamide)(PAAAM)resin was prepared from acrylic acid(AA)and acrylamide(AM)by inverse suspension polymerization.The adsorption of metal ions on PAAAM resin differed greatly at different pH values...Poly(acrylic acid-co-acrylamide)(PAAAM)resin was prepared from acrylic acid(AA)and acrylamide(AM)by inverse suspension polymerization.The adsorption of metal ions on PAAAM resin differed greatly at different pH values and initial concentrations.This provided a theoretical basis for the application of PAAAM resin to separate transitional metal ions Cu2+,Ni2+,Co2+.The selectivity for competitive adsorption on PAAAM resin in Cu2+,Ni2+ and Co2+ binary and ternary mixed ion solutions were investigated.It was found that there was higher selectivity on PAAAM resin for Cu2+ ions compared with other metal ions used in this study.展开更多
The absorbencies (Q) of superabsorbent, prepared from acrylic acid and acrylamide by the solution polymerization method, in Cl- salt solutions were investigated.The results have shown that,Q increased quickly at first...The absorbencies (Q) of superabsorbent, prepared from acrylic acid and acrylamide by the solution polymerization method, in Cl- salt solutions were investigated.The results have shown that,Q increased quickly at first and then increased slowly, and at last became constant in NaCl solutions with an increase of swelling time.However, in transitional metal ionic salt solutions,Q increased at first and then decreased with an increase of swelling time.The relationship between adsorption capacity (q) and adsorption time (t) was investigated, a good linear relation between t/q and t was obtained.The relationship between q and the concentration of Fe 3+(C) was also discussed, and the largest q was 171 mg·g -1 when C was 0.315 mg·ml -1.展开更多
文摘Poly(acrylic acid-co-acrylamide)(PAAAM)resin was prepared from acrylic acid(AA)and acrylamide(AM)by inverse suspension polymerization.The adsorption of metal ions on PAAAM resin differed greatly at different pH values and initial concentrations.This provided a theoretical basis for the application of PAAAM resin to separate transitional metal ions Cu2+,Ni2+,Co2+.The selectivity for competitive adsorption on PAAAM resin in Cu2+,Ni2+ and Co2+ binary and ternary mixed ion solutions were investigated.It was found that there was higher selectivity on PAAAM resin for Cu2+ ions compared with other metal ions used in this study.
文摘The absorbencies (Q) of superabsorbent, prepared from acrylic acid and acrylamide by the solution polymerization method, in Cl- salt solutions were investigated.The results have shown that,Q increased quickly at first and then increased slowly, and at last became constant in NaCl solutions with an increase of swelling time.However, in transitional metal ionic salt solutions,Q increased at first and then decreased with an increase of swelling time.The relationship between adsorption capacity (q) and adsorption time (t) was investigated, a good linear relation between t/q and t was obtained.The relationship between q and the concentration of Fe 3+(C) was also discussed, and the largest q was 171 mg·g -1 when C was 0.315 mg·ml -1.
