摘要
该文选取海藻内2种主要的多糖分子:条浒苔硫酸多糖和羊栖菜褐藻糖胶,采用Py-GC/MS、TG-MS宏观试验和微观分子动力学模拟的方法研究海藻多糖热解过程及其热解主要产物的形成机理,Py-GC/MS试验表明条浒苔多糖的热解产物以呋喃类物质为主,典型产物为5-甲基-糠醛,而羊栖菜多糖的热解产物以酸酯类物质为主。对海藻多糖模型化合物的热解过程进行分子动力学模拟发现热解过程主要发生在中温阶段,温度升高到420 K时,开始有羟基断裂;温度升高到500 K时,糖苷键开始断裂,环状单体内部化学键相继分解成各种分子碎片,由于其成分差异,热解产物也不尽相同,模拟分析的热解规律与试验结果基本一致。该文还结合TG-MS试验结果推导其热解过程中主要气体产物H2O、CO2、SO2的形成机理。
In order to understand the thermal decomposition mechanism of seaweed polysaccharide and the formation mechanism of main products from the micro perspective, two main seaweed polysaccharides molecules,enteromorpha clathrate sulfated polysaccharides andsargassum fusiforme fucoidan were selected. Through Py-GC/MS and TG-MS experiments, the formation mechanism of products was analyzed. Py-GC/MS results showed thatenteromorphaclathrate polysaccharides pyrolysis forms furans mainly, with 5-methyl-furfural as the typical product; while the products ofsargassum fusiforme pyrolysis are mainly polysaccharide acid esters. The polymers builder of hyperchem and the semi-empirical method were used to build and optimize the molecular model of sulfated polysaccharides and fusiforme fucoidan. Then the characteristic parameters of molecules were obtained. Based on amber force field, the pyrolysis processes of the seaweed polysaccharide model compounds were simulated with the molecular dynamic method at 297-1200 K and periodic boundary conditions. The simulation results showed that the pyrolysis of lignin model compound can be divided into three stages: the low temperature stage (below 500 K), the intermediate temperature stage (500-800 K) and the high temperature decomposition stage (above 800 K). It was found that the reaction stage concentrated mainly in the intermediate temperature stage. The simulation results showed that hydroxide radical was produced at about 400 K. And when the temperature was increased to about 500 K, polysaccharides molecular monomers were formed with the break of glucoside bond. At the same time, pyranoid ring was also opened with the formation of various kinds of molecular fragments. The experimental results were basically in agreement with those of pyrolysis simulation. Besides, the formation mechanisms of H2O, CO2, and SO2 during the pyrolysis of seaweed polysaccharides were analyzed combined with TG-MS gas release mass spectrometry. The GC-MS were adopted to analyze the composition of bio-oil w
出处
《农业工程学报》
EI
CAS
CSCD
北大核心
2016年第S2期338-343,共6页
Transactions of the Chinese Society of Agricultural Engineering
基金
国家自然科学基金资助项目(51306078
51676091)
广东省公益研究与能力建设专项(2014A020217008)
国家科技支撑计划资助项目(2015BAD21B06)
关键词
生物质
热解
分子动力学
硫酸多糖
褐藻糖胶
biomas
pyrolysis
molecular dynamic
sulfated polysaccharides
fucoidan
